Wednesday, 5 November 2014

Basics of abrasive polishing

 
Basics of abrasive polishing
Automotive paint surfaces comprise numerous microscopic peaks and valleys, much like the profile of a mountain range. These irregularities are known as capillary structures; there may be millions of these defects per square inch.
When these scratches are removed from a surface it becomes a smooth level surface that reflects light. Scratches are identified by a grit number; "grit" is a reference to the number of abrasive particles per inch of finishing paper that are required to remove the scratches left by the grit scratches i.e. 2000 grit scratches are removed by using an abrasive rated at 3000 grit. You are actually replacing scratches with even finer scratches until they are invisible to the naked eye.
Menzerna manufacture a range of abrasive polishes from 1000 grit all the way down to 4000 grit (SF4000) these polishes contain nanotechnology ceramic micro particle diminishing abrasives that are milled to 0.3 µ (micron) They mill their own abrasives, which allows them to control the size and uniformity of the aluminium oxide abrasive used and also contain a higher abrasive content, 7% were as the other polishes contain 3% abrasives.
The abrasives are just one factor in the equation; lubricants, solvents, emulsion and their carrier system will determine the actual functional ability of the polish. Diminishing abrasive polishes are pad ‘dependent’ as far as its paint correction / renovation abilities are concerned. These polishes were designed to work by utilizing kinetic (or dynamic) friction to break-down the diminishing abrasives, the more friction applied to diminishing abrasives the finer they become; this is how even micro scratches are removed. It works on the surface of paint using aluminium oxide spheres, suspended in water and hydrocarbon oils and a mechanical process to abrade the surface of the paint down to the level of the bottom of the scratch.
Abrasives
The ability for a polish to "cut" depends on the shape of its crystals or particles, not necessarily its size. A medium size, spiked abrasive will tumble and dig. However, a large round crystal won't leave a deep scratch.
Aluminium oxide has a hardness factor MOHS 9 and will not break down during polishing. Rather the larger clusters of aluminium oxide reduce in size. A large hard abrasive may also be brittle. It will cut once and lose its edge, while a softer small abrasive will hold its edge and keep on cutting. Many smaller abrasives have wedge shaped edges protruding from triangular crystals. These can easily slice through an oxidized layer of paint
Types (Grades) of Polish
A surface scratch that will `catch' your fingernail is approximately 0.04 Mil (1.0 µ Microns) deep will usually require wet sanding and refinishing. Other than that > 1000 grit scratches can be removed with a polish/compound and a machine polisher.
The ability for a polish to "cut" depends on the shape of its crystals or particles, not necessarily its size. A medium size, spiked abrasive will tumble and dig. However, a large round crystal won't leave a deep scratch. A large hard abrasive may also be brittle. It will cut once and lose its edge, while a softer small abrasive will hold its edge and keep on cutting. Many smaller abrasives have wedge shaped edges protruding from triangular crystals. These can easily slice through an oxidized layer of metal.
Liquid polishes tend to perform better than pastes because they allow you to use the oxidation you're removing as an abrasive. The oxidation will be no coarser than the abrasive in the polish, and since aluminium oxide is second only to a diamond abrasive, it makes an ideal cutting compound.
1. Compounds
Are the most aggressive, most abrasive type of polish and will remove the largest amount of clear coat in the shortest period of time. Compounds are commonly used on severely neglected vehicles and to clean up wet sanding marks. Compounds will almost always leave behind some marring, hazing, or holograms and should always be followed up with a finer polish or multiple polishes.
2. Abrasive Polishes
Most polishes that correct moderate paint imperfections fall into the category of an abrasive polish. They are a step below compounds in terms of aggressiveness and usually do not finish down as well as a finishing polish. On most paints, it is recommended to follow up an abrasive polish with a finishing polish to remove any micro-marring, hazing or holograms as well as increase the depth and gloss. Some abrasive polishes are capable of finishing on certain paint.
3. Finishing Polishes
A finishing polish will remove very minor imperfections in the paint, such as micro-marring, hazing and holograms. A finishing polish is formulated with a very mild abrasive that finely polishes the paint surface and effectively enhances light refraction and reflectivity. They are also used to burnish (jewelling) the paint to achieve an exceptional level of gloss and depth.
4. Paint Cleaners
A chemical paint cleaner are designed to enhance the depth and gloss while properly preparing the paint for a sealant or wax. Sometimes paint cleaners can have micro abrasives or they can be non-abrasive. They typically will not remove imperfections that require levelling the clear coat, but can remove some oxidation and mineral deposits.
Always choose the least intrusive product, it is preferable to polish 2-3 times to restore the paint film surface than to use an unnecessarily abrasive machine polish / foam pad combination.
Before commencing polishing do a test panel on the car, once you have achieved the desired results with the chosen polish / pad combination proceed
 
 
Amount of polish
I’m certain you’ve all heard the mention of two pea-sized drops on a pad as the correct amount of polish to use.  Now this will work, but not as a starting point.
If you rub a dry pad against your hand, you will notice that very soon your hand gets hot. Be cognizant that each foam pad will have a degree of mechanical cut of its own. A pad without polish can be quite dangerous, easily overheating and burning the paint. My recommendation is to apply a liberal amount of polish to the fresh pad. Then carefully massage it into the face of the pad – often referred to as ‘priming the pad’.
Apply a proper amount of compound, massage it in and get ready to polish. Although this may sound wasteful, this can make all the difference when you actually start polishing:
• All polish will have its own lubrication (oil, wax, polymers or a combination of these) which also helps the pad to run cooler and avoid overheating the paint, which will suit many of the new paint systems that manufacturers are using today. It’s much safer too, especially when working delicate areas like edges because they usually have a thin coat of paint and the extra lubrication may prevent strikethrough or burnt paint
• The whole surface area of the pad is now working, properly cutting for you. No hot/cool areas that could cause problems and inconsistent results. The theory is quite simple; a primed pad is like a piece of sandpaper used for wet-sanding, with the abrasives evenly spread out and it has adequate lubrication.
• Using a primed pad with two dime-sized drops of polish after each polishing stage, clean and re-apply polish to the pad, trying to keep the pad evenly coated with polish ready to polish the next section.
Why is a clean pad so important to the process?
Clean and / or replace pads as often as is necessary; a clean seasoned pad will enhance the abrasive abilities of the compound / polish and make the process not only more efficient but less time consuming. 
The best way to clean a pad is by using compressed air hooked up to a high velocity nozzle. If this option is not possible then brush the pads frequently with a nylon brush while the machine spins the pad. This is important to keep the fibres from matting down as well as prevent contaminated abrasives from clumping together and marring the surface.
Lastly - DO NOT over polish paint; there is only a finite amount of clear coat available

The Phyics of Polishing

 
 
The Physics of Polishing  
Physics (from Ancient Greek: φύσις physis "nature") [: a natural science that involves the study of matter and its motion through space and time, along with related concepts such as energy and force.]
 
 
Backing Plate / Pad Motion
The benefits of a large orbit or elliptical offset is that more centripetal force is created as the backing plate orbits, so the backing plate will rotate more than a similar machine featuring a smaller elliptical offset. A machine featuring a large stroke delivers increased speed of backing plate motion using the same orbits per minute. A large stroke elliptical offset increases movement of the baking plate / pad; therefore levelling is more consistent. This type of pad movement helps to remove residue (oxidized paint, spent abrasives, etc.) more readily than a small elliptical offset
A majority of random orbital machines use an elliptical offset between 1/8 -5/16 - inch (approximately 3.0-8.0 mm). It is generally accepted that a smaller stroke leaves a more refined finish, but experience shows that this type of movement doesn’t readily clear (oxidized paint, spent abrasives, etc. ) polishing debris, thereby blocking the pores of the pad and placing debris between the pad and the paints surface negatively impacting the abrasive
 
Surface (Contact) Area
 
The distance around the circle is a circumference. The distance across the circle is the diameter (d). The radius (r) is the distance from the centre to a point on the circle. (π = 3.14), d = 2(r), c = π d = 2 (p) r, A = π(r) 2 Even a minor change in pad diameter makes a big difference in surface area.
A pad should be designed to efficiently use its surface area. Foam pads that have lines, squares, circles, or dimples cut out of the pad face, means there is less actual surface area in contact with the paint surface. Area = (r2) 6-inch pad area = 18.842 sq.ins a 4-inch pad 12.46 sq.ins.
Kinetic (Heat) and machine energy (Speed) and surface pressure applied over a smaller area, which results in faster correction. A further consideration of pad diameter has to do with distribution of the machine weight and applied pressure.
Another design parameter that determines how much surface area actually contacts the paint when using foam pads is the amount of pores per inch it features (commonly referred to as PPI). More pores, larger pores, thinner walls between the pores, or how stiff the walls are all affect how much foam contacts the paint during the buffing process
Block wet sanding (finishing paper and a sanding block) which ensures a consistent pressure over the surface contact area, this is the most effective method for paint defect removal because of its linear process; you abrade the paint surface flat until the defects are removed.
Pad Velocity (Speed)
The larger the pad, the greater the pad velocity at an identical RPM; V = RPM (Area) A - 6.5-inch = 20.423 sq. ins V= 24,507 inches per minute (IPM) Pad velocity is also substantially increased with a larger diameter pad, which increase its abrasive ability at the outer edge; 8-inch =25.136 sq. ins V= 30,163 RPM
Pressure / Pad Compression
Depending on the types of surface abrasions you're dealing with, increase pressure is necessary; otherwise most of the kinetic energy of the machine will be absorbed by the pad (especially foam) and not transferred to the paint surface.
Just remember that more pressure equals more aggressive, so be careful around ridges and raised surfaces Maintain the same pressure and work the product in, it may take three or four passes to complete before the residue can be removed. Once you see the desired results move on to the next area, or repeat the process as necessary.
The required pressure applied to obtain optimum results to adequately compress the pad (50%) and obtain uniform abrasion is usually in the range of 10 – 15 lbs. (a random orbital buffer will stall at approximately 20 pounds of applied force) use just enough pressure to keep the pad rotating at 1-2 rotations per second.
To compress a 6-inch pad 50% requires you increase the total force by the ratio of its surface areas; Ratio = [π (radius2)] / [π (radius2)] = 2.25 as much force, almost 34 pounds).
With the smaller pad you're applying the same force, at a constant speed but over a smaller, more concentrated area, which will induce friction and greater abrasion abilities to the polish, both these abilities require a certain amount of caution as it’s possible to abrasion burn the paint.
Constant Pressure™ Foam Pads have a layer of engineered, instant rebound foam between the pad and the backing plate. This layer acts as a cushion or shock absorber between the machine, the operator and the surface being worked on. It absorbs off-axis motion while maintaining a constant and uniform pressure on the surface; Lake Country Mfg. Constant Pressure™" technology allows even a neophyte detailer to achieve professional-like results.
Foam Pad Size (Area and Applied Pressure)
Different pad sizes can have an impact on how the buffer breaks down a polish, as it applies its dynamic friction over less area, control, better manoeuvrability, and how fast you can cover an area.
Smaller pads in general will offer you more control with any machine polisher, as it can reduce the tendency for the buffer to hop or skip on the paint. Smaller pads also make it easier to manoeuvre buffers in tighter areas and closer to trim pieces.
The low profile 5.5 inch buffing pads pack the same CCS technology and performance into a compact, highly effective size that works best with dual action polishers and air sanders. Use with a 5 - inch moulded urethane backing plate for excellent flexibility and balance by Lake Country (LC) manufacturing
Assuming equal speed, radius and foam compression (50% - 15 pounds of force applied) the difference between 4- inch and 6 - inch pads is their different surface area = π (r2) (4-inch = 12.46 sq.ins / 6-inch = 28.26 sq.ins) and therefore surface kinetic (or dynamic) friction applied and surface pressure applied; 4-inch = 3.75 lbs per sq.ins - 6-inch = 2.5 lbs per sq.ins.  Even a minor change in pad diameter makes a big difference in surface area.
Actual Speed (RPM)
Formula - RPM (C) = V
Speed = Revolutions per minute, C = circumference (2(π) (r)), V = velocity
Area 7.5 -inch at 1,800 rpm (usable area 6- inches)
Speed - 1,800 (rpm) (6" diameter times pi = 6” x 3.14) x 18.84    = 33,912.
So, using the same formula, and a problem of: X (unknown rpm) x 25.12 (8" diameter times pi = 8” x 3.14) = 33,912) then; 33,912 / 25.12 = 1,350 actual speed rpm
Kinetic Friction
 [ : when contacting surfaces move relative to each other, the friction between the two surfaces converts kinetic energy into thermal energy, or heat]
Friction is the force resisting the relative lateral (tangential) motion of solid surfaces, fluid layers, or material elements in contact. It is usually subdivided into several varieties:
Dry friction is also subdivided into static friction between non-moving surfaces, and kinetic friction (sometimes called sliding friction or dynamic friction) between moving surfaces.
Arrows are vectors indicating directions and magnitudes of forces. W is the force of weight, N is the normal force, F is an applied force of unidentified type, and Ff is the force of kinetic friction which is equal to the coefficient of kinetic friction times the normal force. Since the magnitude of the applied force is greater than the magnitude of the force of kinetic friction opposing it, the block is moving to the left.
Heat from Kinetic (or dynamic) Friction
[Energy in a system may take on various forms (e.g. kinetic, potential, heat, light). Kinetic friction, or surface resistance induced heat; an often misunderstood concept of polishing / compounding; abrasives require friction to breakdown, not heat; heat is just a resultant of friction between two surfaces. Kinetic friction is required to ‘level’ paint, which is simply the removal of paint to the lowest point of the paint defect] [1]
Energy in a system may take on various forms (e.g. kinetic, potential, heat, light). Kinetic friction, or surface resistance induced heat; an often misunderstood concept of polishing / compounding; abrasives require friction to breakdown, not heat; heat is just a resultant of friction between two surfaces, besides the most commonly used abrasives include varieties of aluminium oxide, silicon carbide, diatomaceous earth, clay, and silica, to produce enough heat to cause a reduction in size would harm the paint. Kinetic friction is required to ‘level’ paint, which is simply the removal of paint to the lowest point of the paint defect.
A finishing pad will not provide as much friction as a cutting foam pad (less surface resistance) although they will both produce friction induced heat, whereas a wool pad, due to their composition, creates less friction induced heat but more kinetic friction (due to its fibrous structure) than most foam pads.
Polishing a paint surfaces transfer’s kinetic friction induced heat to the paint surface, thermoplastic polymers have both tensile strength (a linear stress-strain relationship) and elongation (elasticity) which allow the surface to flex, expand and contract in accordance to surrounding temperatures, solvents, resins and other ingredients in polishes will expand causing the paint film surface to expand, temporarily ‘masking’ paint surface defects.
As the metal substrate expands the paint moves with it, due to its elasticity, thereby becoming elongated (thinner) this is part of the cause of friction induced ‘burn’, you’re applying pressure and an abrasive to a less dense (‘thinner’) paint surface, excess friction induced heat can cause the paint surface to burn, blister, haze, and cause excessive swirls. 
[: A thermosetting resin (polymer) is a material that irreversibly cures (hardens) usually by heat, generally above 200 °C (392 °F), through a chemical reaction, or suitable irradiation]
Clear coat are formulated from a thermosetting polymer, when subjected to high ‘spot’ kinetic energy (friction heat) from polishing will cause thermal stress, which causes the paint film to stretch and this negatively affects its structural integrity. Once a polymer has been heat-set it changes change irreversibly to become hard and therefore cannot re-flow. An elevated temperature will cause the lubrication system (oil, wax and and/or the solvents) in the abrasive to evaporate, which will result in dry polishing, driving defects deep into the paint matrix
 Kinetic Friction induced heat can cause a rapid surface temperature rise; (i.e. initial surface temp 80.oF, friction heat attained with the polisher stationary and a cutting foam pad at 1,100 RPM for approx. ten seconds the friction induced heat attained would be around 104.oF) the paint temperature can be checked by utilizing an instant read-out infra-red ‘gun type’ digital thermometer, paint surface ‘spot’ temperature should be limited to 110.oF <
Be cognizant that plastic has a much lower rate of thermal conductivity than metal, so it absorbs heats at a far greater rate and is therefore subject to thermal degradation (burning /deforming).
Polishes and compounds do not need heat per se for the abrasives to polish a surface, wither they be diminishing or non-diminishing abrasive, they require both pressure and friction
In accordance with the Society of Automotive Engineers (SAE) a localized (spot) temperature of > 115.oF will cause the urethane clear coat to soften and the foam pad will cause scratching that is forced deep into the clear coat.(See also the first law of thermodynamics et al) [/I]
The Ideal Gas Laws
 
Polishing Freshly Applied Paint
When a urethane clear coat is sprayed its outermost surface, measuring a few nanometres in thickness, sustains microscopic fractures when it comes into contact with air. These fractures are microns or nanometres in width and thus too small to be seen with the unaided eye.
Freshly applied paint that in the outgas stage, is still full of evaporating solvents, and is usually less dense (soft) despite the additives used (hardener) once a catalyst, kinetic energy (friction heat) is added, it causes the paint film to expand, temporarily hiding scratches, this is often the reason for a body-shops bad reputation of returning vehicles that have sanding scratches in newly applied paint that should have been removed.
Be cognizant when polishing newly applied paint the kinetic energy (heat) from a foam pad can also cause solvent engorgement, which causes the paint film to thin due to the expansion of the evaporating gases, applied rotational force may also cause the paint to tear Kinetic friction (heat) is transferred to a solvent (isopropyl alcohol (IPA) or fresh paint solvents) causing it to both expand (Charles' law; also known as the law of volumes) the paint film and soften it.
Automotive paint is classified as a semi-permeable membrane; it has both tensile strength and elongation (elasticity) newly painted surfaces are soft and full of out gassing solvents, resin binders and additives, as well as and water.
Polish contains solvents, which soften the paint film, kinetic surface friction and applied downward pressure transfers its energy into heat / torque (force to rotate an object about an axis), which could result in the alteration of the paint films bond between its substrate, causing it to delaminate or tear?   
 
The heat makes the gasses expand (pV = nRT) the expanding gases go through a phase transition (change in density) and to relive this increased pressure they (a) rupture the paint film surface, causing small fissures (similar to solvent pop) Theheat may cause the gaseous vapours to expand, but not enough to break through the hardening clear coat.  
Once the vapour has evaporated, it may leave a void between the basecoat and the clear.  Therefore you have a cloudy spot where the clear and base is no longer adhered together. If this is the case, the clear coat will delaminate in the future.
Once the outgas process is complete automotive coatings (paint) becomes a semi-solid permeable membrane, Being a polymer (elastomers) it remains flexible while retaining its tensile strength, to enable it to expand and contract to follow temperature fluctuations of the substrate (elongation). Kinetic friction and its associated heat can cause a rapid temperature rise (i.e. initial surface temp 80.oF, heat attained with a cutting foam pad at 1,100 RPM for approx. ten seconds is approx. 104.oF) the paint temperature can be checked by utilizing an instant read-out infra-red ‘gun’ thermometer, paint surface ‘spot’ temperature should be limited to 110.oF <
 
Applied Pressure
The pad needs to have an even distribution of pressure applied to it; depending on the types of surface abrasions you're dealing with, increase pressure as necessary. Just remember that more pressure equals more aggressive, so be careful around ridges and raised surfaces
Maintain the same pressure and work the product in, it may take three or four passes to complete before the residue can be removed. Once you see the desired results move on to the next area, or repeat the process as necessary.
The required pressure applied to obtain optimum results to adequately compress the pad (50%) and obtain uniform abrasion is usually in the range of 10 – 15 lbs. (a random orbital buffer will stall at approximately 20 pounds of applied force) To compress a 6-inch pad 50% requires you increase the total force by the ratio of its surface areas
Ratio = [π (radius2)] / [π (radius2)] = 2.25 as much force, almost 34 psi). With the smaller pad you're applying the same force, at a constant speed but over a smaller, more concentrated area, which will induce  an increase in friction and greater abrasion abilities to the polish / pad combination, both these abilities require a certain amount of caution as it’s possible to ‘strike through’ (friction burn)  the paint.
 
Hardness
So how can a dense (hard) clear coat be so easily scratched?
 It’s a matter of physics, not material density (material hardness). Force acts through a body that has a surface area; if the surface area is really small while maintaining an equal force, the pressure becomes astronomical and the object under pressure capable of penetrating the surface of an otherwise tough material.
 
 
Newton's third law of motion [: when a first body exerts a force F1 on a second body, the second body simultaneously exerts a force F2 = −F1 on the first body. This means that F1 and F2 are equal in magnitude and opposite in direction]
That’s why a micro fine thread that is twice as fine as silk and a 100 times finer than a human hair, in an otherwise soft towel will scratch your paint. And the same reason a mosquito can penetrate a rhino hide with its proboscis (stinger).
If you press down on your paint finish with your palm it feels really hard and tough, but that’s because the surface area of your palm is relatively large and what you’re actually feeling is the resistance of the steel underneath the paint. Try pressing your thumb nail into the paint with the same amount of force you used with your palm, if you dare.
Relevant Articles
1.       “Paint (Solvent / Alcohol) Swelling”
 
2.       “Wipe down (Scratch lie detector test) Process”
 
3.       TOGWT® Autopia Detailing Wiki articles
I hope these TOGWT Detailing Wiki articles will become an asset to anyone who is new to detailing and to the professionals; enthusiast detailer’s and industry experts who seek to advance their knowledge of detailing entry level enthusiast, but to professionals and industry experts as well.
 
 

Thursday, 23 October 2014

Automotive Silica Coatings




Silica Coating
[: The hydrophobicity of a surface is determined by the contact angle. The higher the contact angle the higher the hydrophobicity of a surface. Surfaces with a contact angle < 90° are referred to as hydrophilic and those with an angle >90° as hydrophobic. Some plants show contact angles up to 160° and are called super-hydrophobic meaning that only 2-3% of a drop's surface is in contact. Plants with a double structured surface like the lotus can reach a contact angle of 170° whereas a droplet’s actual contact area is only 0.6%. All this leads to a self-cleaning effect.
Dirt particles with an extremely reduced contact area are picked up by water droplets and are thus easily cleaned off the surface. If a water droplet rolls across such a contaminated surface the adhesion between the dirt particles, irrespective its chemistry, and the droplet is higher than between the particle and the surface]
Paint sealants compared to Coatings
Automotive paint surfaces are porous and contain microscopic peaks and valleys, much like the profile of a mountain range. These irregularities are known as capillary structures; there may be millions of these defects per square inch. Contaminants such as fine dirt, minerals, and pollutants are drawn into the voids where they are extremely hard to remove.
Paint sealants are synthetic products designed for long-term paint protection and easy application. They are composed mainly of amino functional polymers, which last longer than any natural wax and are highly resistant to the elements. Synthetic liquid waxes are another way of describing paint sealants. The main benefit of a paint sealant is their durability compared to a wax, polymer-based sealants will last anywhere from 3 to 6 months.
A coating is applied to a clean surface that surface takes on properties that are virtually identical to hardened glass. It is chemically inert and will not react with the base material. In other words, dirt will not bond to the treated surface, thereby reducing soiling and organic staining. Acid rain and other chemical compounds easily wash off, significantly reducing the hydroscopic nature of surfaces exposed to industrial or environmental pollution.
Hydrophobic surface [: The requirements for a self-cleaning hydrophobic surface are a very high static water contact angle θ, the condition often quoted is θ>160°, and a very low roll-off angle, i.e. the minimum inclination angle necessary for a droplet to roll off the surface] [1]
Repellant [: able to repel a particular thing; impervious to a particular substance]
The lotus effect [: refers to self-cleaning properties that are a result of very high water repellence (super- hydrophobicity), as exhibited by the leaves of the lotus flower] Dirt particles are picked up by water droplets due to the micro architecture on the surface, which minimizes the droplet's adhesion to that surface
Silica Coating consist of four chemicals – Silicon (Si), Siloxane (H(OSiH2)n OH), Silane (SiH4 ) and Silazane(a silicone compound), once formulated they become Silicon Dioxide (SiO2) they are marketed under various brand names:  AQuartz  is an inorganic silica / silicon dioxide, G|techniq is an inorganic silicate crystallization compound, Nanolex is an  inorganic, solvent-based nanostructure coating, Opti-Coat™ is a polymer-based (Si02) coatings. DuPont's SupraShield™, PPG's Optech™ and CeramiClear™ are all inorganic silica automotive paint coatings.
Be cognizant that there are many glass coats in the market today and many of them can all be traced back to one or two suppliers
Silica coating are a clear liquid in a molecular form that is held in a polymer solvent carrier system. This silica is aerobic (hardens on contact with air) and becomes glass. Multi-chemical component coatings interlace on a molecular basis and form an extremely durable protective layer on the paint surface provided they are applied properly. These coatings are chemically inert and are highly resistant to a range of chemicals both acid to Ph. 2.0 and alkali to Ph. 13.5  acid, they also offer resistance to solvents, and they are very durable and capable of obtaining a surface thickness of Mils (µ (microns) to be verified
When a silica coating is applied to a clean surface, that surface takes on properties that are virtually identical to hardened glass. It is chemically inert and will not react with the base material. In other words, dirt will not bond to the treated surface, thereby reducing soiling and organic staining.
Acid rain, bird excrement and other chemical compounds easily wash off, significantly reducing the hydroscopic nature of surfaces exposed to industrial or environmental pollution.
The paint surface is porous and contains microscopic peaks and valleys, much like the profile of a mountain range. These irregularities are known as capillary structures. Contaminants such as fine dirt, minerals, and pollutants are drawn into the voids where they are extremely hard to remove. Capillary structures also provide microbes and bacteria with an excellent place to grow and multiply.
A silica coating fills the capillary structures, which produces a smooth flat hydrophobic surface. (A hydrophobic surface is one that repels moisture.) In contrast, a hydrophilic surface is one that absorbs moisture. The potential of a surface to absorb or repel moisture is based on many factors, including: temperature, relative humidity, material homogeneity, and static electricity. Surface roughness is also a major factor; the rougher the surface, the higher the spreading rate or attraction for water. The smoother the surface, the more repellent it is to moisture.
Some formulations of Liquid glass contain titanium dioxide for extra shine without affecting durability. These micro-particles of titanium dioxide reflect light of specific wavelengths, producing an instant luminous shine and gloss. Titanium dioxide is sensitive to photocatalyzation and produces traces of active oxygen when exposed to ultra violet (UV) radiation. This effect helps the coating to prevent the attachment of contaminants to the paint. This means that, in most instances, environmentally damaging cleaning chemicals are not needed.
Silicosis happens by breathing the dust particulates of glass, which cut and scar the lungs, causing damage, which results in diminished lung capacity. So where does the silicon dioxide enter into this equation as a safe product to breathe when applied as a spray? 
Liquid glass is actually a mixture of caustic soda, quartz sand, and water are prepared in a mixing tank, then fed into a reactor, where steam is introduced. The reaction is (n SiO2 + 2 NaOH → Na2O•nSiO2 + H2O). Sodium silicate is spherical silica in a liquid state, which essentially means ‘liquid glass’ crystals which are smooth and round instead of sharp and pointed.
Because there are no sharp edges to damage lung tissue it is relatively safe to breath. But why would we think it is safe to fill our lungs with round glass any more than with jagged sharp glass particles? Do the lungs have the ability to process and get rid of the ‘spherical’ shapes through the blood stream? 
Is ‘liquid silicon dioxide’ really ‘colloidal silica,’ or is it ‘sodium silicate’?  Silicon dioxide = SiO2 and Sodium silicate = Na2SiO3. Colloidal silica is simply the liquid spherical shape of silicon dioxide while sodium silicate is silicon dioxide with an added salt element (Na). Both products are derived from the second most abundant element on Earth – sand.
I would strongly suggest you do not breathe it in but use the appropriate personal protection. If you were to examine the urethane clear coat with high-performance electron- microscope, you would see lots of fissures or micro holes. Nano sized silica glass particles penetrate these fissures to form a mechanical anchor with the clear coat, creating a durable finish that won't fracture
Modesta P-01A and BC-04 Nano-Titanium Glass coating - is definitely a worthy investment if your vehicles appearance is important to you. An advanced and very unique glass coating, it forms a highly durable, clear hard glass layer on automotive paints. BC-05 produces a deep shine and helps to protect the paint from all kinds of damage including wash-induced damages, scratches, oxidation, sap, watermarks, salts, acids and even permanent ink and paints. Its strong water-repellent properties also promote the self-cleaning (Lotus effect).  Used stand-alone as a sealant, BC-05 produces a unique candy-like gloss. If combined with the P-01A primer this effect is even deeper as the layers of both products are combined to a single coat. It can be applied even to the most advanced and sophisticated paints, such as Nissan Scratch Shield, Lexus’ self-restoring coat and Mercedes ceramic paint. Durability is claimed to be in excess of 10 years.
Product Application
Use the appropriate personal protection equipment (PPE) an approved mask (Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance) nitrile gloves and safety glasses as a minimum
My preferred application method is to use base coating (P-01A) applied with a rotary machine polisher and apply the coating with a spray gun as I feel this gives a consistent thickness and coverage. The coating can be applied with a micro fibre towel but the major disadvantage of this type of application is the coating dries and solidifies to glass, which means you need 5- 8 towels that will be discarded after use.
Drying / Curing
Use of infra-red lamps is highly recommended
Allow 24 hours on a moisture / dust free environment

Maintenance

Using a specially formulated product like Optimum No Rinse (ONR) by using 1 oz. of ONR to 2 gallons of water, when using a rinse bucket, there is no need to add ONR to the second bucket. However, you should wring the towel well after rinsing so that you do not dilute the wash bucket. This will help to effectively clean your coating and it rinses away easily without leaving behind gloss enhancers or other surfactants.  This is an ideal coating maintenance shampoo


Optimum Opti-Mitt is a soft, nonabrasive 8 Inch Foam Wash Mitt designed to work with ONR to remove grime without scratching. The porous foam absorbs dirt and road oil to prevent paint marring. The coarse yellow foam is excellent at cleaning wheels. Use the Opti-Mitt every time you wash your vehicle for safe, swirl-free washing.
Summary
Silica coatings offers superior durability, hydrophobicity, surface hardness and scratch resistance, resistance to environmental contaminants and works in a similar way to a clear coat in providing ultra violet (UV) and heat radiation protection without colour change (yellowing) or oxidation and easier maintenance, simply rinsing with plain water results in a clean surface without loss of gloss. I think these products will have a profound impact and radically change auto detailing
Bibliography
1.      Royal Society of Chemistry (RSC) Library & Information Centre
2.      Glossary of Chemical Terms - Faculty of Chemical Technology
3.      Basic Concepts of Nanotechnology, History of Nano-Technology, News, Materials and Potential Risks
4.      Lotus-inspired nanotechnology applications, B. Karthick1  and Ramesh Maheshwari
5.      SpecialChem4 Polymers
6.      Macromolecular Chemistry and Physics
7.      European Coatings Handbook 2nd Edition, by Brock, Groteklaes, Mischke
8.      Bayer Material Science, Automotive  eNewsletters (Coating, Adhesives and Specialties)
The information in this article is based on the current status of the technical development as well as our experience with the products.
*  Copyright © TOGWT ® 2002-2010, all rights reserved